Hexachloroethane C2Cl6 CAS 67-72-1

Hexachloroethane is a white camphor-scented powder used as solvent, degassing agent for Al/Mg/Cu alloys, smoke agent, rubber accelerator, and veterinary anthelmintic. Also used in pesticide, pharmaceutical, and PVC plasticizer synthesis. Insoluble in water.
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Hexachloroethane (C₂Cl₆) – Versatile Solvent and Industrial Intermediate

Basic Information

  • Product Name: Hexachloroethane (Perchloroethane)

  • CAS Number: 67-72-1

  • Synonyms: C₂Cl₆, Egitol, Front 110, NA 9037, Distopin, Distopan, Distokal, CCl₃CCl₃, Falctitol, Phenohep

  • Molecular Formula: C₂Cl₆

  • Molecular Weight: 236.74 g/mol

  • Appearance: White crystalline powder with a camphor-like odor

  • Solubility: Soluble in ethanol, ether, benzene, chloroform, and oils; insoluble in water.

Overview
Hexachloroethane (HCE) is a chlorinated hydrocarbon widely used in various industrial and chemical applications. Its high chlorine content, stability, and reactivity make it a valuable intermediate and additive in multiple fields, including metallurgy, agriculture, pharmaceuticals, and rubber processing.

Applications

  • Solvent and chemical intermediate: Used as a solvent and raw material for the production of fluorine-113, pesticides, pharmaceuticals, and veterinary drugs.

  • Smoke generators: When mixed proportionally with zinc powder, ammonium chloride, and ammonium perchlorate, HCE forms effective smoke‑producing compositions for military and signaling applications.

  • Metallurgy: Acts as a degassing and deoxidizing agent for aluminum, magnesium, copper, and their alloys, removing hydrogen and oxides to improve metal quality.

  • Rubber industry: Used as a substitute for camphor in celluloid and as a vulcanization accelerator.

  • PVC processing: Employed as a plasticizer additive and in lubricant formulations.

  • Veterinary medicine: HCE itself serves as an insecticide and anthelmintic, primarily used in treating liver and stomach diseases in ruminants, as well as schistosomiasis and nematode infections.

  • Foam suppression: Used as a defoaming agent and degassing agent in various industrial processes.

Key Properties

  • High chemical stability under normal conditions.

  • Low solubility in water, but readily dissolves in organic solvents.

  • Sublimes at moderate temperatures, making it suitable for smoke generation.

  • Toxic and should be handled with appropriate safety measures.

Handling and Storage

  • Store in a cool, dry, well-ventilated area, away from strong oxidizers and reducing agents.

  • Keep containers tightly sealed to prevent contamination and moisture absorption.

  • Use appropriate personal protective equipment (gloves, safety goggles, respirator) when handling.

  • Avoid inhalation of dust and contact with skin and eyes.

Packaging
Available in 25 kg, 50 kg, and 200 kg drums, or custom packaging upon request.

Quality Assurance
Each batch is tested for purity (by GC), moisture content, and melting point to ensure consistent quality.

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