Polymethyl Methacrylate (PMMA) – Transparent Thermoplastic for Optics, Electronics, and Architecture
Basic Information
CAS Number: 9011-14-7
Molecular Formula: (C₅H₈O₂)ₙ (repeating unit)
Appearance: Colorless transparent granules or finished transparent sheets
Density: ~1.18 g/cm³
Glass Transition Temperature: ~105°C
Melting Point: ~160°C (softens)
Solubility: Insoluble in water; soluble in organic solvents such as acetone and dichloromethane
UV Resistance: Excellent
Storage: Store in a dry place, protected from moisture
Overview
Polymethyl methacrylate (PMMA), commonly known as acrylic glass or Plexiglas, is a transparent thermoplastic polymer derived from methyl methacrylate. It is renowned for its exceptional optical clarity, light transmission, and UV resistance, making it a popular alternative to glass in many applications. PMMA is lightweight, impact-resistant, and easily molded, which contributes to its widespread use in electronics, architecture, signage, medical devices, and optical components. Its chemical stability and weather resistance ensure long-lasting performance in both indoor and outdoor environments.
Applications
Architecture and construction: Glazing, skylights, sound barriers, and decorative panels.
Electronics: Display screens, light guides, and protective covers for devices.
Medical: Dental prosthetics, bone cements, contact lenses, and surgical instruments.
Optics: Lenses, prisms, and optical fibers.
Signage and advertising: Illuminated signs, displays, and point-of-sale materials.
Automotive: Tail lights, instrument panels, and exterior trim.
Key Benefits
High optical clarity – transmits up to 92% of visible light.
Excellent UV resistance – does not yellow or degrade under sunlight.
Lightweight – about half the weight of glass.
Impact-resistant – more durable than glass.
Easy to mold and machine – suitable for complex shapes and precise parts.
Chemically resistant to many acids, alkalis, and salts.
Recyclable and environmentally manageable.
Handling and Storage
Store in a cool, dry place, away from moisture and direct sunlight.
Keep away from strong solvents that may cause swelling or dissolution.
Use appropriate personal protective equipment (gloves, safety goggles) when machining or heating.
Avoid overheating above 300°C to prevent decomposition and release of methyl methacrylate monomer.
Shelf life: typically 24 months under recommended storage conditions.
Quality Assurance
Each batch is tested for molecular weight, transparency, and mechanical properties to ensure consistent quality.