Polyglyceryl-2 Laurate – Mild Non-Ionic Emulsifier for Stable Cosmetic and Personal Care Formulations
Basic Information
INCI Name: Polyglyceryl-2 Laurate
CAS Number: 33940-99-7 (common for polyglyceryl-2 laurate; specific grade may vary)
Synonyms: Diglyceryl monolaurate, Polyglycerol-2 laurate, PG-2 Laurate
Appearance: Pale yellow to amber viscous liquid or waxy solid
HLB Value: ~8–10 (oil-in-water emulsifier)
Solubility: Dispersible in water and oils; soluble in organic solvents
Storage: Store in tightly sealed containers in a cool, dry place, protected from light and moisture
Chemical Structure and Synthesis
Polyglyceryl-2 laurate is a non-ionic monoester produced by the esterification of polyglycerin-2 (diglycerin) with one molecule of lauric acid. The synthesis can be represented as:
PG₂ + Lauric Acid → Polyglyceryl-2 Laurate + H₂O
where PG₂ denotes polyglycerin-2. The retention of free hydroxyl groups ensures water solubility, while the lauryl chain provides lipophilicity, creating an optimal balance for effective emulsification.
Overview
Polyglyceryl-2 laurate is a versatile non-ionic emulsifier derived from renewable plant-based sources. Its amphiphilic structure effectively reduces interfacial tension between oil and water, forming stable oil-in-water (O/W) emulsions with fine, uniform texture. This mild, biodegradable surfactant is widely used in cosmetic, personal care, and pharmaceutical formulations for its excellent emulsifying, dispersing, and conditioning properties.
Key Properties
Non-ionic – compatible with a wide range of ingredients and pH levels.
Amphiphilic – reduces interfacial tension, stabilizing O/W emulsions.
Optimal HLB (8–10) – suitable for oil-in-water systems.
Mild and non-irritating – suitable for sensitive skin and baby products.
Excellent dispersing and stabilizing properties.
Thermal and chemical stability – resistant to hydrolysis and oxidation.
Biocompatible and low toxicity – safe for topical applications.
Biodegradable and derived from renewable plant-based sources.
Provides smooth, elegant textures with a pleasant skin feel.
Applications
Cosmetics and personal care: Used as a primary or co-emulsifier in O/W creams, lotions, serums, sunscreens, makeup removers, and hair care products. Provides stable, elegant textures with good spreadability, moisturizing properties, and emollient benefits.
Pharmaceuticals: Employed as an emulsifier, solubilizer, and excipient in topical ointments, creams, and suppositories.
Food industry: Used as a food additive (E475) and emulsifier in margarines, spreads, sauces, dressings, and baked goods. Improves texture, stability, and mouthfeel.
Industrial: Applied as a dispersant, lubricant, and stabilizer in specialty chemical formulations.
Key Benefits
Effective O/W emulsification with excellent stability.
Mild and non-irritating – suitable for sensitive skin and baby products.
Emollient properties – conditions and softens skin and hair.
Excellent spreading and moisturization.
Thermal and chemical stability – reliable performance over time.
Biocompatible, biodegradable, and of natural origin.
Compatible with a wide range of cosmetic, food, and pharmaceutical ingredients.
Acts as a co-emulsifier, thickener, and stabilizer in complex formulations.
Recommended Use
Typical usage levels range from 1–5% of the formulation, depending on the desired emulsion stability, viscosity, and texture. For optimal performance, dissolve in the oil phase at elevated temperatures (60–70°C) before emulsification. Can be combined with co-emulsifiers and thickeners for tailored rheology.
Safety and Handling
Generally recognized as safe (GRAS) for use in food and cosmetics at recommended concentrations.
Low irritation potential; well-tolerated by skin and mucous membranes.
Avoid contact with strong oxidizers and acids.
Store in a cool, dry place, away from direct sunlight.
Use appropriate personal protective equipment (gloves, safety goggles) when handling.
Quality Assurance
Each batch is tested for acid value, saponification value, and emulsification performance to ensure consistent quality.