Polyglyceryl-10 Dilaurate – Lipophilic Non-Ionic Diester Emulsifier for Stable Emulsions
Basic Information
INCI Name: Polyglyceryl-10 Dilaurate
CAS Number: 34406-66-1 (common for polyglyceryl laurates; specific grade may vary)
Synonyms: Decaglyceryl dilaurate, Polyglycerol-10 dilaurate, PG-10 Dilaurate
Appearance: Pale yellow to amber viscous liquid or waxy solid
HLB Value: ~6–8 (lipophilic, suitable for W/O and O/W emulsions)
Solubility: Soluble in oils and organic solvents; dispersible in water
Storage: Store in tightly sealed containers in a cool, dry place, protected from light and moisture
Chemical Structure and Synthesis
Polyglyceryl-10 dilaurate is a non-ionic diester produced by the esterification of polyglycerin-10 (decaglycerin) with two molecules of lauric acid. The synthesis can be represented as:
PG₁₀ + 2 Lauric Acid → Polyglyceryl-10 Dilaurate + 2 H₂O
where PG₁₀ denotes polyglycerin-10. The substitution of two hydroxyl groups with lauryl chains significantly enhances lipophilicity, while the remaining free hydroxyl groups retain sufficient hydrophilicity for balanced amphiphilic properties.
Overview
Polyglyceryl-10 dilaurate is a versatile non-ionic emulsifier derived from renewable plant-based sources. Its dual lauryl chains provide enhanced lipophilicity, making it particularly effective for water-in-oil (W/O) and oil-in-water (O/W) emulsion systems. This mild, biodegradable surfactant imparts smooth, elegant textures with a pleasant skin feel and is suitable for sensitive skin formulations.
Key Properties
Non-ionic – compatible with a wide range of ingredients and pH levels.
Amphiphilic – reduces interfacial tension, stabilizing both W/O and O/W emulsions.
Enhanced lipophilicity – suitable for oil-rich and emollient formulations.
Mild and non-irritating – suitable for sensitive skin and baby products.
Excellent emulsifying, dispersing, and stabilizing properties.
Thermal and chemical stability – resistant to hydrolysis and oxidation.
Biocompatible and low toxicity – safe for topical applications.
Biodegradable and derived from renewable plant-based sources.
Provides smooth, elegant textures with a pleasant skin feel.
Applications
Cosmetics and personal care: Used as a primary or co-emulsifier in W/O and O/W creams, lotions, serums, sunscreens, makeup removers, and hair care products. Provides stable, elegant textures with good spreadability, moisturizing properties, and emollient benefits.
Pharmaceuticals: Employed as an emulsifier, solubilizer, and excipient in topical ointments, creams, and suppositories.
Food industry: Used as a food additive (E475) and emulsifier in margarines, spreads, sauces, dressings, and baked goods. Improves texture, stability, and mouthfeel.
Industrial: Applied as a dispersant, lubricant, and stabilizer in specialty chemical formulations.
Key Benefits
Effective emulsification for both W/O and O/W systems.
Mild and non-irritating – suitable for sensitive skin and baby products.
Emollient properties – conditions and softens skin and hair.
Excellent spreading and moisturization.
Thermal and chemical stability – reliable performance over time.
Biocompatible, biodegradable, and of natural origin.
Compatible with a wide range of cosmetic, food, and pharmaceutical ingredients.
Acts as a co-emulsifier, thickener, and stabilizer in complex formulations.
Recommended Use
Typical usage levels range from 1–5% of the formulation, depending on the desired emulsion stability, viscosity, and texture. For optimal performance, dissolve in the oil phase at elevated temperatures (60–70°C) before emulsification. Can be combined with co-emulsifiers and thickeners for tailored rheology.
Safety and Handling
Generally recognized as safe (GRAS) for use in food and cosmetics at recommended concentrations.
Low irritation potential; well-tolerated by skin and mucous membranes.
Avoid contact with strong oxidizers and acids.
Store in a cool, dry place, away from direct sunlight.
Use appropriate personal protective equipment (gloves, safety goggles) when handling.
Quality Assurance
Each batch is tested for acid value, saponification value, and emulsification performance to ensure consistent quality.