Hydrogen Dimethicone (CAS 68037-59-2)

A silicone fluid and surface treatment agent. Provides a silky feel, enhances spreadability, forms a protective barrier, and improves water repellency in cosmetics.
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Hydrogen Dimethicone – Modified Silicone Fluid for Cosmetic Applications

Basic Information

  • CAS Number: 68037-59-2 (also 69013-23-6, 70900-21-9)

  • INCI Name: Hydrogen Dimethicone

  • Synonyms: Dimethicone/Methicone Copolymer, Dimethylhydropolysiloxane

  • Appearance: Clear, colorless, odorless fluid

  • Viscosity: ~20 mm²/s (at 25°C)

  • Specific Gravity: 0.971 (at 25°C)

  • Refractive Index: 1.398 (at 25°C)

  • Solubility: Insoluble in water

  • Storage: Store in a cool, dry place, away from direct sunlight and moisture

Overview
Hydrogen Dimethicone is a derivative of dimethicone where some of the methyl groups have been replaced with hydrogen atoms. It is a versatile silicone fluid widely used in cosmetics as an emollient, skin-conditioning agent, and surface treatment agent. Its lightweight, non-greasy nature makes it ideal for a wide range of applications, including skincare, haircare, and makeup formulations.

Synthesis
Hydrogen Dimethicone is typically synthesized by reacting dimethicone with hydrogen gas in the presence of a catalyst, resulting in the replacement of some methyl groups with hydrogen atoms.

Key Properties

  • Skin conditioning: Acts as an effective emollient, imparting a silky, smooth texture to skin and hair.

  • Enhanced spreadability: Improves the even distribution of products, facilitating smooth application.

  • Protective barrier: Forms a lightweight, breathable film that helps retain moisture and protect the skin.

  • Water repellency: Optimizes water resistance, making it valuable in waterproof and long-wear formulations.

  • Surface treatment: Used to treat powder particles, improving their hydrophobicity, adhesion, and feel.

  • Reduced greasiness: Helps reduce the greasy feel of cosmetic products, providing a luxurious, non-oily finish.

  • Non-comedogenic: Does not clog pores and is unlikely to cause acne.

  • Lightweight: Its lightweight nature makes it suitable for lotions, creams, and foundations.

Applications

  • Skincare: Lotions, creams, serums, and sunscreens – provides a silky feel, enhances spreadability, and improves the even distribution of UV filters.

  • Haircare: Shampoos, conditioners, and styling products – tames frizz and adds shine without greasiness.

  • Makeup: Foundations, powders, and primers – used as a surface treatment agent for powders, improving water repellency, adhesion, and feel.

  • Color cosmetics: Enhances the texture and performance of powder foundations and other pigmented products.

  • Other: Acts as a film-forming agent, lubricant, and anti-foaming agent in various formulations.

Recommended Use
Typical usage levels range from 1–3% of the formulation, depending on the desired effect. For optimal performance, incorporate into the oil phase or use as a surface treatment for powders.

Safety and Handling

  • Generally recognized as safe for use in cosmetics at recommended concentrations.

  • Low irritation potential; non-comedogenic and well-tolerated by skin.

  • Avoid contact with strong oxidizers.

  • Store in a cool, dry place, away from direct sunlight and moisture.

  • Use appropriate personal protective equipment (gloves, safety goggles) when handling.

Quality Assurance
Each batch is tested for viscosity, specific gravity, refractive index, and volatile content to ensure consistent quality.

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