Cocamidopropyl Dimethylamine – Cationic Surfactant and Conditioner for Hair and Skin Care
Basic Information
CAS Number: 68140-01-2
Synonyms: Amides, coco, N-[3-(dimethylamino)propyl]; Cocoyl propyl dimethyl tertiary amine
Molecular Formula: C₁₇H₂₀N₄O₂ (typical)
Appearance: Clear to slightly hazy liquid or paste (depending on concentration)
Solubility: Dispersible in water upon protonation (acidification); soluble in oils and organic solvents
Overview
Cocamidopropyl dimethylamine is a tertiary amine surfactant derived from coconut fatty acids and 3-dimethylaminopropylamine (DMAPA). Its amphiphilic structure – featuring a lipophilic coconut fatty acid chain and a hydrophilic tertiary amine group – provides a unique combination of conditioning, emulsifying, and antistatic properties. It is widely used in personal care formulations as a mild cationic surfactant and conditioning agent.
Applications
Hair care: Conditioners, shampoos, leave‑in treatments, and hair masks – improves wet and dry combability, softness, and shine; reduces static and frizz.
Skin care: Creams, lotions, and moisturizers – provides emollient and smoothing effects.
Emulsions: Stabilizes O/W and W/O systems, improving product consistency and texture.
Cleansing products: Body washes, facial cleansers – enhances foam texture and skin feel.
Industrial: Used in foaming agents, thickening agents, ore flotation, and quaternary ammonium salt production.
Key Benefits
Provides excellent conditioning and antistatic properties.
Enhances softness and manageability of hair.
Stabilizes emulsions and improves product texture.
Mild and low irritation – suitable for sensitive skin.
Cold-processable – easy to incorporate into formulations.
Plant‑derived coconut fatty acid base – renewable and biodegradable.
Recommended Use
Typical usage levels range from 0.5–3% in rinse‑off products and 1–5% in leave‑on formulations. For optimal performance, incorporate into the oil phase with mild heating (50–60°C). It can be neutralized with acids (e.g., citric acid, lactic acid) to form cationic salts, enhancing water dispersibility and conditioning efficacy.
Safety and Handling
Generally recognized as safe for use in cosmetics at recommended concentrations.
Low irritation potential; well‑tolerated by skin and eyes.
Avoid contact with strong oxidizers and acids.
Store in a cool, dry place, away from direct sunlight.
Use appropriate personal protective equipment (gloves, safety goggles) when handling.
Quality Assurance
Each batch is tested for amine value, purity, and conditioning performance to ensure consistent quality.